Determination of the absolute configuration of (+)-2,7(14),10-bisabolatrien-1-ol-4-one from Japanese cedar, Cryptomeria japonica.

نویسندگان

  • Chul-Sa Kim
  • Jun Morisawa
  • Nobuhiro Nishiyama
  • Takehiro Kashiwagi
  • Shin-ich Tebayashi
  • Michio Horiike
چکیده

The absolute configuration of (+)-2,7(14),10-bisabolatrien-1-ol-4-one, a peculiar sesquiterpenol in the Japanese cedar, Cryptomeria japonica, was determined as (1S,6R)-2,7(14),10-bisabolatrien-1-ol-4-one by comparing the specific rotation values of cryptomeriones respectively converted from (+)-2,7(14),10-bisabolatrien-1-ol-4-one and synthesized from (R)-(-)-carvone.

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عنوان ژورنال:
  • Bioscience, biotechnology, and biochemistry

دوره 66 9  شماره 

صفحات  -

تاریخ انتشار 2002